Compressed Gas Leak Test Procedure – Stanford Environmental Health & Safety (2024)

How to use this tool

How to use this tool

At Stanford University, all toxic gas cylinders will be tested for leaks prior to removing cylinders from the delivery vehicle, if possible. Also, non-toxic gas cylinders such as flammables should be tested for leaks before acceptance. Leaking gas cylinders will not be accepted. The Principal Investigator (PI) who ordered the gas cylinder is responsible for ensuring that the cylinder is leak tested. Similarly, all compressed gas experimental apparatus should be leak tested periodically per the applicable experimental protocol. Only individuals trained in the use of leak detection methods should perform this leak test procedure.

Leak Detection Methods

The preferred andprimary methodfor leak detection is a direct reading instrument with a sensor that uses thermal conductivity different from that of the ambient air for detection, such as the Matheson LeakHunter Plus Model 8066 or its equivalent. This type of detector is highly sensitive and can locate leaks too small to bubble quickly with a liquid solution leak detector.

Compressed Gas Leak Test Procedure – Stanford Environmental Health & Safety (1)

Gases and vapors with thermal conductivity different from air can be detected with this method, and some are listed in the table below.

Analternate method, if the primary method cannot be used, is liquid solution leak detection such as the Matheson Detect-A-Leak™ or equivalent that meets or exceeds MIL-L-25567D Type I andII specifications.

GasDetection limitACGIH TLV TWA (ppm)
GasDetection limitACGIH TLV TWA (ppm)
Acetone10 cc/min500
Ammonia5 ppm25
Arsine0.3 ppm0.05
Benzene10 cc/min0.5
Carbon Monoxide1 ppm25
Chlorine7 ppm0.5
Diborane0.15 ppm0.1
11-Dichloroethane10 cc/min100
Ethanol10 c/min1000
Ethylene1 cc/minN/A
Ethylene Oxide350 ppm1
Formaldehyde10 cc/minC 0.3
Freon 121 cc/min1000
n-Hexane10 cc/min50
Hydrogen10 ppmN/A
Hydrogen Bromide1 ppmC 3
Hydrogen Chloride1 ppmC 5
Hydrogen Selenide0.5 ppm0.05
Hydrogen Sulfide1 ppm10
Isopropyl Alcohol10 cc/min400
Methane1 cc/minN/A
Methyl Bromide40 ppm1
Methyl Chloride50 ppm50
Methyl Ethyl Ketone (MEK)10 cc/min200
Phosphine0.13 ppm0.3
Propane1 cc/min2500
Silane0.3 ppm5
Sulfur Dioxide1 ppm2
Toluene10 cc/min50
Trichloroethylene10 cc/min50
Vinyl Chloride10 ppm5
Xylene10 cc/min100
Compressed Gas Leak Test Procedure – Stanford Environmental Health & Safety (2024)
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